The High Voltage Conductivity of The Binary Mixtures of Alkaline Metals Hydrosulphates In a Solid and Liquid Phases

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The High Voltage Conductivity of The Binary  Mixtures of Alkaline Metals  Hydrosulphates In a Solid  and Liquid Phases

Abstract. The influence of high  voltage pulse discharges passing through binary mixtures of alkaline metals hydrosulphates in a solid  and liquid phases on their conductivity has been  investigated. The phenomenon  of  high voltage activity  of the investigated  electrolytes is discovered. It proved  by  a relative increase of the conductivity. The extent of activation reaches  75-243% for binary  proton solid  electrolytes systems and 24-325 % for corresponding melts (depending  of their composition and temperature).
Besides that the “memory” effect  is established which was seen in maintaining  of excess conductivity for a long  period of time. The kinetic of relaxation  process  of excess conductivity of proton  solid electrolytes (PSE) and their  melts has been  studied. The relaxation times of the non-equilibrium charge carry in these electrolytes varies within the range of (0.35-2.15)∙104s for PSE and (0.69-4.4)∙104s for their melts.